The invention relates to a synthesis method of modified [alpha]-methylstyrene resin with a high softening point for improving wet skid resistance of rubber, and belongs to the technical field of rubber composition additives. In the synthesis process of the modified [alpha]-methyl styrene resin, under the presence of initiators, modifier styrene and dicyclopentadiene are added, two or more of ethylidene norbornene and norbornene are used for modifying [alpha]-methyl styrene to prepare the intermediate product, the reaction condition is mild, the intermediate product and a chain extender are further reacted to prepare the modified [alpha]-methylstyrene resin, the reaction temperature is appropriate, the temperature control is easy, the synthesis method is suitable for continuous production,the softening point of the prepared resin is high, good wet skid resistance is provided on the premise of maintaining the basic physical properties of the tire.

    本发明涉及一种高软化点、用于提高橡胶抗湿滑性能的改性α‑甲基苯乙烯树脂的合成方法,属于橡胶组合物添加剂技术领域。本发明提供的改性α‑甲基苯乙烯树脂的合成过程中,在引发剂的存在下,添加改性剂苯乙烯与双环戊二烯,乙叉降冰片烯,降冰片烯中的两种或多种对α‑甲基苯乙烯进行改性,制备得到中间产物,反应条件温和,然后将该中间产物与扩链剂进一步反应制备得到改性的α‑甲基苯乙烯树脂,其反应温度适宜,易于控温,适合连续生产,制备树脂软化点高,同时在保持轮胎的基本物理性能的前提下提供较好的抗湿滑性能。


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    Title :

    Synthesis method of modified [alpha]-methylstyrene resin with high softening point for improving wet skid resistance of rubber


    Additional title:

    一种高软化点、用于提高橡胶抗湿滑性能的改性α-甲基苯乙烯树脂的合成方法


    Contributors:
    YAO XIANG (author) / PENG HUALONG (author) / XU LIMING (author) / RONG CHUNYONG (author)

    Publication date :

    2020-04-28


    Type of media :

    Patent


    Type of material :

    Electronic Resource


    Language :

    Chinese


    Classification :

    IPC:    C08F MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS , Makromolekulare Verbindungen, erhalten durch Reaktionen, an denen nur ungesättigte Kohlenstoff-Kohlenstoff-Bindungen beteiligt sind / B60C VEHICLE TYRES , Fahrzeugreifen / C08K Verwendung von anorganischen oder nichtmakromolekularen organischen Stoffen als Zusatzstoffe , USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS / C08L COMPOSITIONS OF MACROMOLECULAR COMPOUNDS , Massen auf Basis makromolekularer Verbindungen




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