In order to overcome deficiencies of phenomenological models of batteries for electric vehicles, this paper analyses models based on electrochemical laws. Considering one space coordinate, there are essentially two approaches: (i) macrohomogeneous and (ii) single-pore models. It is shown that they are equivalent under general assumptions. A macrohomogeneous model of a valve-regulated lead/acid battery is calculated for a highly dynamic discharge current pattern. Simulated voltage as a function of time matches experimental results, but further work is necessary, especially in a careful determination of several empirical parameters. Finally, battery models restricted to ordinary differential equations are discussed as an approximation of spatial models
Electrochemical modelling of lead/acid batteries under operating conditions of electric vehicles
Elektrochemische Modellierung von Blei-Säure-Batterien unter Betriebsbedingungen von Elektrofahrzeugen
1997
6 Seiten, 22 Quellen
Conference paper
English
Electrochemical modelling of lead-acid batteries under operating conditions of electric vehicles
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