A promising method to extract oxygen from CO2, which constitutes more than 95% of the Mars atmosphere, is by using glow-discharge dissociation of CO2 combined with the permeation of the generated oxygen through a Ag membrane. Quadrupole mass spectrometry was utilized to measure the oxygen flux through a 0.35-mm-thick, 2.01 cm2 area membrane separating a two-chamber system. On the upstream side of the membrane, a dc glow discharge was established with 350 V and 5 mA current. It was found that as much as 75% of the CO2 was dissociated to form CO and O (part of which recombined to form O2). The atomic and molecular oxygen generated were adsorbed on the membrane surface, subsequently dissolved into the Ag, and diffused through the membrane thickness to the downstream surface where it desorbed as molecular oxygen. The resulting oxygen flux was studied as a function of upstream CO2 pressure, discharge current, discharge probe to membrane distance, and membrane temperature. It was found that the atomic oxygen generated a much higher concentration gradient across the membrane than did the molecular oxygen which resulted in a correspondingly higher oxygen flux through the membrane. The total oxygen flux through the membrane with a CO2 glow-discharge pressure of 5 Torr and a membrane temperature of 450 degrees C was found to be greater than 1014 cm-2 s-1. This method can be used to continuously and efficiently supply oxygen for astronauts in a future manned mission to Mars.
Extraction of oxygen from CO2 using glow-discharge and permeation techniques
Erzeugung von Sauerstoff aus CO2 mit Hilfe einer Glimmentladung und Diffusion durch eine Membran zum Einsatz in der bemannten Raumfahrt
1996
7 Seiten, 15 Quellen
Article (Journal)
English
Kohlendioxid , Sauerstoff , Glimmentladung , Dissoziation , Astronomie , chemische Reduktion , chemische Reaktion , Membran , Silber , Diffusionskoeffizient , Massenspektrometrie , chemische Lösung , Adsorption , Oberflächenstruktur , Desorption , Temperaturgang , Porosität , Raumfahrt , Gasanalyse , Analysenmesstechnik , Elektrochemie , Erdatmosphäre , Gasatmosphäre , Planet , Luft , Kohlenstoffverbindung , Diffusion , massenspektrochemische Analyse
A Study of Glow-Discharge and Permeation Techniques for Extraterrestrial Oxygen Beneficiation
Online Contents | 1994
|A Study of Glow-Discharge and Permeation Techniques for Extraterrestrial Oxygen Beneficiation
British Library Conference Proceedings | 1994
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