Abstract It is found that carbamyl phosphate is an efficient condensing agent for acetate and hydroxylamine in the presence of $ Be^{2+} $ and $ Al^{3+} $. The reaction has an optimum at pH 4 and is completed within 30 min. The yield of hydroxamate formation reaches 30% (based on initial carbamyl phosphate). Acetylphosphate as the intermediary product of this reaction was identified by P-NMR spectroscopy.


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    Title :

    Nonenzymatic phosphorylation of acetate by carbamyl phosphate


    Contributors:

    Published in:

    Publication date :

    1983




    Type of media :

    Article (Journal)


    Type of material :

    Print


    Language :

    English



    Classification :

    Local classification TIB:    535/3908/4290
    BKL:    44.71 Verkehrsmedizin




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