We report a total‐area power conversion efficiency of 15% for a copper indium gallium disulfoselenide (CIGSSe) solar cell fabricated from a copper indium gallium disulfide (CIGS) nanoparticle ink based process. Careful optimization of the fabrication process has resulted in a significant improvement in efficiency compared to our previously reported efficiency of 12%. This efficiency ranks among the highest reported in the literature for solution processed CIGSSe. Despite having an absorber thickness of approximately 700–800 nm, which is less than half the thickness of high efficiency devices grown by both coevaporation and solution processes in the literature, our devices show good short‐circuit current (32.1 mA/cm 2 ). Surprisingly, the sintered film shows lateral composition fluctuations, which have not been reported for other high efficiency devices and may be responsible for the lower open circuit voltage (636 mV) observed here. This suggests an avenue for further improvement through optimization of the nanoparticle selenization process to better control composition in the sintered film. Copyright © 2015 John Wiley & Sons, Ltd. In this work we report total‐area power conversion efficiency of 15% for CIGSSe solar cells fabricated from nanoparticle inks. This efficiency is among the highest for solution processed CIGSSe and is a significant improvement over our previously reported efficiency of 12%. However, we have characterized spatial composition fluctuations in the CIGSSe absorber layers which may be a factor limiting device performance. This suggests an avenue towards further improvement by removing these fluctuations.


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    Title :

    Synthesis and characterization of 15% efficient CIGSSe solar cells from nanoparticle inks



    Published in:

    Publication date :

    2015




    Type of media :

    Article (Journal)


    Type of material :

    Print


    Language :

    English



    Classification :

    BKL:    53.36 Energiedirektumwandler, elektrische Energiespeicher