Free-standing GaN substrates has been prepared by hydride vapor phase epitaxy (HVPE) technology. Round substrates with diameters up to 1.5 inch and thickness up to 350 micron can be achieved. Various measurement tools, including X-ray diffraction, atomic force microscopy (AFM), and etch pit density (EPD) measurement, have been applied to characterize the optical and the structural properties of these substrates. The typical full width at half maximum of the PL spectra and the [002] X-ray diffraction peak was 10 nm and 120 arcsec respectively, compared to the typical values of 10 nm and 200 arcsec obtained on epitaxial GaN layers grown by metalorganic chemical vapor deposition (MOCVD) technique on Al/sub 2/O/sub 3/ substrates. Yellow bands usually detected in PL spectra can be eliminated, indicating reduction of related point defects. AFM measurements revealed a surface roughness of 5 nm or larger after growth and separation. With proper polish, the surface roughness can be reduced to less than 1 nm. EPDs on these substrates can be as low as in the 10/sup 5/ cm/sup -2/ range, compared to the typical values of 10/sup 8/-10/sup 10/ cm/sup -2/observed in MOCVD GaN layers grown on Al/sub 2/O/sub 3/ substrates. Without doping, the free-standing GaN substrates showed electron concentrations less than 10/sup 16/ cm/sup -3/. But with proper doping, electron concentration as high as 10/sup 19/ cm/sup -3/, and hence resistivity lower than 0.1 /spl Omega/-cm, can be achieved. Maximum electron mobilities higher than 800 cm/sup 2//V-sec and 400 cm/sup 2//V-sec were detected in lightly doped and heavily doped substrates respectively. In this paper, the procedure of producing these free-standing GaN substrates will be briefly described, and the above measurement results, along with their indications, will be discussed.


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    Title :

    Study of free-standing GaN substrates prepared by hydride vapor phase epitaxy technology


    Contributors:
    Tsung Yu Chen, (author) / Cheng-Ta Kuo, (author) / Chi-Ling Lee, (author) / Wei-I Lee, (author)


    Publication date :

    2003-01-01


    Size :

    209799 byte




    Type of media :

    Conference paper


    Type of material :

    Electronic Resource


    Language :

    English



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