This invention relates to production of propylene-predominant copolymers using a transition metal complex and at least two different non-coordinating anion activators. An olefinic feed comprising a C3-C40 alpha olefin, ethylene, and a diene monomer is contacted under polymerization reaction conditions with a catalyst system comprising a first non-coordinating anion activator, a second non-coordinating borate activator differing from the first non-coordinating anion activator, and a transition metal complex comprising a tetrahydro-s-indacenyl or tetrahydro-as-indacenyl group bound to a group 3-6 transition metal. A molar ratio of the first non-coordinating anion activator to the second non-coordinating anion activator is sufficient to produce a melt flow rate under the polymerization reaction conditions for the resulting copolymer of about 30 g/10 min or below as determined by ASTM D-1238 (230° C., 2.16 kg).
Multiple non-coordinating anion activators for propylene-ethylene-diene monomer polymerization reactions
2021-07-06
Patent
Electronic Resource
English
IPC: | C08F MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS , Makromolekulare Verbindungen, erhalten durch Reaktionen, an denen nur ungesättigte Kohlenstoff-Kohlenstoff-Bindungen beteiligt sind / B60C VEHICLE TYRES , Fahrzeugreifen / C08J Verarbeitung , WORKING-UP / C08L COMPOSITIONS OF MACROMOLECULAR COMPOUNDS , Massen auf Basis makromolekularer Verbindungen / C09J ADHESIVES , Klebstoffe |
Low ethylene amorphous propylene-ethylene-diene terpolymer compositions
European Patent Office | 2019
|LOW ETHYLENE AMORPHOUS PROPYLENE-ETHYLENE-DIENE TERPOLYMER COMPOSITIONS
European Patent Office | 2018
|LOW ETHYLENE AMORPHOUS PROPYLENE-ETHYLENE-DIENE TERPOLYMER COMPOSITIONS
European Patent Office | 2016
|European Patent Office | 2022
|