Abstract Reactions of neutral vanadium oxide clusters with (1) methanol, ethanol, (2) alkenes, and (3) NOx and NH3, in a flow tube reactor, are investigated by time of flight mass spectroscopy experiments and density functional theory (DFT). Single photon ionization through using a compact soft x-ray (46.9 nm, 26.5 eV) laser is employed to detect both neutral cluster distributions and reaction products. Results and insights to catalytic processes are presented.
Gas Phase Studies of Catalytic Processes Involving Vmon Clusters and their Reaction with Alcohols, Alkenes, Nox, and Nh3 Using a Desk-Top Size Soft X-Ray Laser
2009-01-01
7 pages
Aufsatz/Kapitel (Buch)
Elektronische Ressource
Englisch
Vanadium Oxide , Tantalum Oxide , Catalysis Today , Flight Mass Spectrometer , Single Photon Ionization Physics , Optics and Electrodynamics , Atomic, Molecular, Optical and Plasma Physics , Quantum Optics , Laser Technology, Photonics , Atoms and Molecules in Strong Fields, Laser Matter Interaction , Plasma Physics
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