Abstract Reactions of neutral vanadium oxide clusters with (1) methanol, ethanol, (2) alkenes, and (3) NOx and NH3, in a flow tube reactor, are investigated by time of flight mass spectroscopy experiments and density functional theory (DFT). Single photon ionization through using a compact soft x-ray (46.9 nm, 26.5 eV) laser is employed to detect both neutral cluster distributions and reaction products. Results and insights to catalytic processes are presented.


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    Titel :

    Gas Phase Studies of Catalytic Processes Involving Vmon Clusters and their Reaction with Alcohols, Alkenes, Nox, and Nh3 Using a Desk-Top Size Soft X-Ray Laser


    Beteiligte:
    Heinbuch, S. (Autor:in) / Dong, F. (Autor:in) / Bernstein, E. R. (Autor:in) / Rocca, J. J. (Autor:in)

    Erschienen in:

    X-Ray Lasers 2008 ; 7 ; 445-451


    Erscheinungsdatum :

    2009-01-01


    Format / Umfang :

    7 pages





    Medientyp :

    Aufsatz/Kapitel (Buch)


    Format :

    Elektronische Ressource


    Sprache :

    Englisch





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