Synthetic porous materials, that is, carbon materials, inorganic solids, and coordination polymers (or metal-organic frameworks, MOFs), have been a focus of research for the pas few decades. A family of discrete metallo-supramolecular nanoballs containing different divalent metals is produced by self-assembly. These species have porous structures, similar to metal-organic frameworks. Stepwise desolvation results in bare metal sites which can be functionalized with organic molecules; the interball cavities show high affinity for hydrogen gas.
Systematic metal variation and solvent and hydrogen-gas storage in supramolecular nanoballs
Angewandte Chemie International Edition ; 48 , 47 ; 8919-8922
2009
4 Seiten, 6 Bilder, 19 Quellen
Article (Journal)
English
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