Reactions using the high nitrogen heterocycle 3,4,5-triamino-1,2,4-triazole (guanazine) with strong acids (HNO3, HClO4, and "HN(NO2)2") resulted in a family of highly stable salts. All of the salts were characterized using spectroscopic as well as single crystal X-ray diffraction studies. The X-ray structures were compared to that obtained from theoretical calculations (MP2/6-311+G(d, p) level). Initial safety testing (impact, friction) was carried out on all of the new materials.
Structural and theoretical investigations of 3,4,5-triamino-1,2,4-triazolium salts
Propellants, Explosives, Pyrotechnics ; 30 , 5 ; 329-337
2005
9 Seiten, 91 Quellen
Article (Journal)
English
Stickstoff , anorganisches Salz , Einkristall , Röntgenbeugung , Urheberrecht , Fachzeitschrift , Erforschung , Beugung (Strahl) , Dioxid , Reibung , Gefahrstoff , Gift , Herbicid , Kohlenstoffverbindung , Kristall , Nichtmetalle , Nichtmetalloxid , Nichtmetallverbindung , Oxid , Pestizid , Sauerstoffverbindung , Sicherheit , Stickoxid , Stickstoffdioxid , Stickstoffverbindung , Strahlungswechselwirkung , Triazol , Tribologie , Wechselwirkung , anorganische Stickstoffverbindung , anorganische Verbindung , chemische Verbindung
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