Abstract The photochemical reaction of HCN at 184.9 nm is studied in the gas phase. (CN)2, $ H_{2} $, $ CH_{4} $, $ NH_{3} $, $ N_{2} $$ H_{4} $, $ C_{2} $$ H_{6} $, and $ CH_{3} $$ NH_{2} $ are identified as gas phase products, and a reaction mechanism is proposed. HCN $ polymers^{**} $ are also obtained as solid reaction products, and their structure is investigated by Infrared Spectroscopy, UV-Visible Spectroscopy, Mass Spectrometry, and Amino acid Analysis. The process and nature of the formation of the polymers are discussed.


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    Title :

    Study on the photochemical reaction of HCN and its polymer products relating to primary chemical evolution


    Contributors:

    Published in:

    Publication date :

    1975




    Type of media :

    Article (Journal)


    Type of material :

    Print


    Language :

    English



    Classification :

    Local classification TIB:    535/3908/4290
    BKL:    44.71 Verkehrsmedizin



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