The U.S. Department of Energy's (DOE) Hydrogen Storage Engineering Center of Excellence (HSECoE) is developing models for hydrogen storage systems for fuel cell-based light duty vehicle applications for a variety of promising materials. These transient models simulate the performance of the storage system for comparison to the DOE's Technical Targets and a set of four drive cycles. PNNL developed models to simulate the performance and suitability of slurry-based chemical hydrogen storage materials. The storage systems of both a representative exothermic system based on ammonia borane and an endothermic system based on alane were developed and modeled in Simulink®. Once complete, the reactor and radiator components of the model were validated with experimental data. The system design parameters were adjusted to allow the model to successfully meet a highway cycle, an aggressive cycle, a cold–start cycle, and a hot drive cycle. Finally, a sensitivity analysis was performed to identify the range of material properties where these DOE targets and drive cycles could be met. Materials with a heat of reaction >11 kJ mol−1 H2 generated and a slurry hydrogen capacity of >11.4% will meet the on-board efficiency and gravimetric capacity targets, respectively.
Development and validation of a slurry model for chemical hydrogen storage in fuel cell vehicle applications
Journal of Power Sources ; 271 ; 504-515
2014
12 Seiten, 23 Quellen
Aufsatz (Zeitschrift)
Englisch
Wasserstoffspeicherung , Brennstoffzelle , Fahrzeug , Amminboran , Empfindlichkeitsanalyse , Fahrzyklus , experimentelle Daten , Systemparameter , Brennstoffzellenfahrzeug , Speichersystem , Aufbewahrungssystem , transientes Modell , Reaktoreinzelteil , Reaktionswärme , Wasserstoff , Personenkraftwagen
Slurry-based chemical hydrogen storage systems for automotive fuel cell applications
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