A detailed chemical kinetic mechanism was used to simulate the oxidation of 1-butene, 2-butene, and isobutene under motored engine conditions. Predicted species concentrations were compared to measured species concentrations obtained from a motored, single-cylinder engine. The chemical kinetic model reproduced correctly the trends in the measured species concentrations. The computational and experimental results showed the main features of olefin chemistry: radical addition to the bond leads to the production of the observed carbonyls and epoxides. For isobutene oxidation, the production of unreactive, 2-methyl allyl radicals leads to higher molecular-weight species and chain termination.


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    Titel :

    Autoignition Chemistry of C4 Olefins Under Motored Engine Conditions: A Comparison of Experimental and Modeling Results


    Weitere Titelangaben:

    Sae Technical Papers


    Beteiligte:
    Westbrook, C.K. (Autor:in) / Pitz, W.J. (Autor:in) / Leppard, W.R. (Autor:in)

    Kongress:

    International Fuels & Lubricants Meeting & Exposition ; 1991



    Erscheinungsdatum :

    01.10.1991




    Medientyp :

    Aufsatz (Konferenz)


    Format :

    Print


    Sprache :

    Englisch





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