Palladium is well known to catalyze methane (CH4) oxidation more efficiently than platinum (Pt) and/or rhodium (Rh) catalysts. The mechanism for methane oxidation on palladium is hypothesized to proceed via a radical intermediate. Direct identification of a radical species was not detected by Electron Spin Resonance Spectroscopy (ESR). However, indirect evidence for a radical intermediate was found by identification of ethane (C2H6), the methyl radical(CH3 ˙ ) coupling product, by Mass spectroscopy analysis under CH4/O2 conditions.


    Zugriff

    Zugriff prüfen

    Verfügbarkeit in meiner Bibliothek prüfen

    Bestellung bei Subito €


    Exportieren, teilen und zitieren



    Titel :

    Development of Methane Oxidation Catalyst and Its Mechanism


    Weitere Titelangaben:

    Sae Technical Papers


    Beteiligte:
    Nagata, Makoto (Autor:in) / Tanaka, Yasushi (Autor:in) / Banno, Yasuyuki (Autor:in) / Hirasawa, Yoshiro (Autor:in)

    Kongress:

    SAE 2005 World Congress & Exhibition ; 2005



    Erscheinungsdatum :

    11.04.2005




    Medientyp :

    Aufsatz (Konferenz)


    Format :

    Print


    Sprache :

    Englisch




    DEVELOPMENT OF METHANE OXIDATION CATALYST AND ITS MECHANISM

    Hirasawa, Y. / Tanaka, Y. / Banno, Y. et al. | British Library Conference Proceedings | 2005


    Optimization of Chromium Oxide/Cobalt Oxide Catalyst for Methane Oxidation

    Depiak, A. M. / Wierzba, I. / Canadian Society for Mechanical Engineering | British Library Conference Proceedings | 1998



    Development of a Sulfur Tolerant PGM Based Zeolite Catalyst for Methane Oxidation and Low Temperature Hydrocarbon Trapping

    Guliaeff, A. / Wanninger, K. / Klose, F. et al. | British Library Conference Proceedings | 2013


    Development of a Sulfur Tolerant PGM Based Zeolite Catalyst for Methane Oxidation and Low Temperature Hydrocarbon Trapping

    Guliaeff, Alexander / Tissler, Arno / Klose, Frank et al. | SAE Technical Papers | 2013