Abstract It is found that carbamyl phosphate is an efficient condensing agent for acetate and hydroxylamine in the presence of $ Be^{2+} $ and $ Al^{3+} $. The reaction has an optimum at pH 4 and is completed within 30 min. The yield of hydroxamate formation reaches 30% (based on initial carbamyl phosphate). Acetylphosphate as the intermediary product of this reaction was identified by P-NMR spectroscopy.


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    Titel :

    Nonenzymatic phosphorylation of acetate by carbamyl phosphate


    Beteiligte:
    Saygin, Ömer (Autor:in)

    Erschienen in:

    Erscheinungsdatum :

    1983




    Medientyp :

    Aufsatz (Zeitschrift)


    Format :

    Print


    Sprache :

    Englisch



    Klassifikation :

    Lokalklassifikation TIB:    535/3908/4290
    BKL:    44.71 Verkehrsmedizin




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