Abstract It is found that carbamyl phosphate is an efficient condensing agent for acetate and hydroxylamine in the presence of $ Be^{2+} $ and $ Al^{3+} $. The reaction has an optimum at pH 4 and is completed within 30 min. The yield of hydroxamate formation reaches 30% (based on initial carbamyl phosphate). Acetylphosphate as the intermediary product of this reaction was identified by P-NMR spectroscopy.
Nonenzymatic phosphorylation of acetate by carbamyl phosphate
Origins of life ; 13 , 1
1983
Aufsatz (Zeitschrift)
Englisch
Lokalklassifikation TIB: | 535/3908/4290 | |
BKL: | 44.71 Verkehrsmedizin |
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