Cu 2 ZnSnS 4 (CZTS)‐based materials have a useful band gap and a high absorption coefficient; however, their power conversion efficiency is low compared with that of CdTe and Cu(In,Ga)Se 2 ‐based solar cells. Two of the factors that strongly affect CZTS solar cell characteristics are the MoS 2 layer and the presence of defects. In this study, Mo back‐contact layers were annealed to control MoS 2 layer formation and the Na content in the Mo layer before the absorber precursor layer was deposited. The increase in oxygen content in the Mo layer suppressed MoS 2 layer formation. In addition, the increase in Na diffusion during the initial stage of the absorber precursor deposition decreased the defect density in the absorber layer and in the absorber–buffer interface. These results were verified through measurements of the external quantum efficiency, the temperature dependence of the open‐circuit voltage ( V OC ), and admittance spectra. The current densities ( J SC ) and V OC , as well as the power conversion efficiencies, improved as the annealing temperature of the Mo layer increased, which suggests that CZTS solar cell characteristics can be improved by suppressing MoS 2 layer formation and increasing Na content in the Mo layer before deposition of the absorber precursor layer. Copyright © 2014 John Wiley & Sons, Ltd. The Mo‐layer annealing temperature is a determining factor for the suppression of MoS 2 formation and for the alternation of the Na content in the diffusion from the soda lime glass into the Mo layers. The solar cell characteristics improve in inverse proportion to the MoS 2 thickness and in direct proportion to the Na content in a Mo layer before absorber precursor layer deposition. The Na reduces the defect density within the absorber and within the absorber–buffer interface.


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    Titel :

    Effects of Na and MoS2 on Cu2ZnSnS4 thin‐film solar cell



    Erschienen in:

    Erscheinungsdatum :

    2015




    Medientyp :

    Aufsatz (Zeitschrift)


    Format :

    Print


    Sprache :

    Englisch



    Klassifikation :

    BKL:    53.36 Energiedirektumwandler, elektrische Energiespeicher