There has been investigated the impact of the nature of substitutes upon the thermodynamic and kinetic stability of “guest-host” complexes between a number of calix[4]arene derivatives and the С60 fullerene by the ММ+ method. It has been established that the availability of branched alkyl or aryl groups in 4-position of a calixarene nucleus increases the system stability. There has been also investigated the influence of the substitute’s nature in the lower ring of a calixarene upon its conformation stability and complexing ability.  


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    Titel :

    Design complexes calixarenes with fullerenes c60




    Erscheinungsdatum :

    2006




    Medientyp :

    Aufsatz (Zeitschrift)


    Format :

    Elektronische Ressource


    Sprache :

    Unbekannt




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