There has been investigated the impact of the nature of substitutes upon the thermodynamic and kinetic stability of “guest-host” complexes between a number of calix[4]arene derivatives and the С60 fullerene by the ММ+ method. It has been established that the availability of branched alkyl or aryl groups in 4-position of a calixarene nucleus increases the system stability. There has been also investigated the influence of the substitute’s nature in the lower ring of a calixarene upon its conformation stability and complexing ability.
Design complexes calixarenes with fullerenes c60
2006
Aufsatz (Zeitschrift)
Elektronische Ressource
Unbekannt
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