Sputtering of Zn(O,S) from ZnO/ZnS compound targets has been proven to be a promising buffer layer process for Cd‐free CIGS modules due to easy in‐line integration, low cost and high efficiency on lab scale. In this publication, we report on successful upscaling of the lab process to pilot production. A record aperture efficiency of 13.2% has been reached on a 50 × 120 cm 2 sized module. Neither a non‐doped ZnO layer nor additional annealing steps are required. Moreover, this very reproducible process yields a standard deviation comparable with that of the CdS base line. In contrast to lab experiments, strong performance gain after light soaking has been observed. The light‐soak‐induced power increase depends on the preparation of the window layer. Accelerated aging tests show high stability of module power. This is confirmed by outdoor testing for 20 months. Copyright © 2017 John Wiley & Sons, Ltd. We have successfully replaced the wet‐chemical CdS buffer by Zn(O,S) on CIGS absorbers. The cadmium‐free process is reproducible, and the electrical data of the full‐size solar modules are stable. Moreover, the dry Zn(O,S) buffer causes lower operational expenditure compared with CdS and allows further upscaling.
Sputtered Zn(O,S) buffer layers for CIGS solar modules—from lab to pilot production
Progress in photovoltaics ; 25 , 8
2017
Aufsatz (Zeitschrift)
Englisch
CIGS , Soaking , Aging (artificial) , Accelerated tests , Modules , Cadmium , Buffer layers , Sputtering , zinc sulfide , Zinc sulfides , Accelerated aging tests , buffer layer , Low cost , sputtering , Zn(O,S) , Cd‐free , Annealing , Solar generators , Zinc oxide
BKL: | 53.36 Energiedirektumwandler, elektrische Energiespeicher |
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